AJL Pombeiro
John Wiley & Sons
e druk, 2014
9781118510148
Advances in Organometallic Chemistry and Catalysis – The Silver/Gold Jublilee International Conferen ceon Organometallic Chemistry Celebratory Book
The Silver / Gold Jubilee International Conference on Organometallic Chemistry Celebratory Book
Specificaties
Gebonden, 736 blz.
|
Engels
John Wiley & Sons |
e druk, 2014
ISBN13: 9781118510148
Rubricering
Verwachte levertijd ongeveer 9 werkdagen
Samenvatting
Commemorating the 25th edition and the 50th year of the prestigious International Conferences on Organometallic Chemistry,
Advances in Organometallic Chemistry provides a snapshot of the hottest topics in organometallic chemistry today. This compilation contains contributions from selected, renowned, and invited speakers, addressing the preparation and use of organometallics in cutting–edge application areas. Suitable for students and practitioners, the book outlines the principles and general properties of organometallic compounds, as well as including practical information on reaction mechanisms and detailed descriptions of contemporary applications.
Specificaties
Inhoudsopgave
<p>PREFACE xi</p>
<p>CONTRIBUTORS xv</p>
<p>PART I ACTIVATION AND FUNCTIONALIZATION OF CARBON SINGLE BONDS AND OF SMALL<br /> MOLECULES 1</p>
<p>1 Organometallic Complexes as Catalysts in Oxidation of C H Compounds 3<br /> Georgiy B. Shul pin</p>
<p>2 Toward Functionalization of Alkanes Under Environmentally Benign Conditions 15<br /> Armando J. L. Pombeiro</p>
<p>3 Self–assembled Multicopper Complexes and Coordination Polymers for Oxidation and Hydrocarboxylation of Alkanes 27<br /> Alexander M. Kirillov, Marina V. Kirillova, and Armando J. L. Pombeiro</p>
<p>4 Activation of C O and C F Bonds by Pincer–iridium Complexes 39<br /> Jason Hackenberg, Karsten Krogh–Jespersen, and Alan S. Goldman</p>
<p>5 Functionalization of sp2 and sp3 Carbon Centers Catalysed by Polyoxometalates and Metalloporphyrins 59<br /> M´ario M. Q. Sim oes, Isabel C. M. S. Santos, Maria Gra¸ca P. M. S. Neves, Ana M. V. Cavaleiro, and Jos´e A. S. Cavaleiro</p>
<p>6 Quasi–borinium Cation Based on Cobalt Bis(dicarbollide): Its Lewis Acidity and C H and C X Bond Activation 73<br /> V. I. Bregadze, I. B. Sivaev, I. D. Kosenko, I. A. Lobanova, Z. A. Starikova, and I. A. Godovikov</p>
<p>7 Transition–metal–promoted Functionalization of Carboranes 81<br /> Zaozao Qiu and Zuowei Xie</p>
<p>8 Weak Interactions and M H Bond Activation 97<br /> Elena Shubina, Natalia Belkova, Oleg Filippov, and Lina Epstein</p>
<p>PART II ORGANOMETALLIC SYNTHESIS AND CATALYSIS 111</p>
<p>9 Complexes with Protic N–Heterocyclic Carbene (NR,NH–NHC) Ligands 113<br /> F. Ekkehardt Hahn</p>
<p>10 Cyclopentadienyl–functionalized N–Heterocyclic Carbene Complexes of Iron and Nickel: Catalysts for Reductions 133<br /> Beatriz Royo</p>
<p>11 Palladium–(acyclic diaminocarbene) Species as Alternative to Palladium–(nitrogen heterocyclic carbenes) in Cross–coupling Catalysis 145<br /> Vadim P. Boyarskiy, Konstantin V. Luzyanin, and Vadim Yu. Kukushkin</p>
<p>12 Synthesis of Metallocenes Via Metathesis in Metal Coordination Spheres 157<br /> Antoni Pietrzykowski and W©©odzimierz Buchowicz</p>
<p>13 Metal–mediated [2 + 3] Dipolar Cycloaddition to Substrates with CN Triple Bond: Recent Advances 171<br /> Konstantin V. Luzyanin and Maxim L. Kznetsov</p>
<p>14 Coordination Chemistry of Oxazoline/Thiazoline–based P,N Ligands 185<br /> Shuanming Zhang, Roberto Pattacini, and Pierre Braunstein</p>
<p>15 Click Copper Catalyzed Azide–alkyne Cycloaddition (CuAAC) in Aqueous Medium 199<br /> Joaqu´©¥n Garc´©¥a–A´lvarez and Jose´ Gimeno</p>
<p>16 Organogold Catalysis: Homogeneous Gold–catalyzed Transformations for a Golden Jubilee 207<br /> Fabien Gagosz</p>
<p>17 Vanadium(IV) Complexes Derived from Aromatic o–Hydroxyaldehydes and Tyrosine Derivatives: Catalytic Evaluation in Sulfoxidations 227<br /> Jo ao Costa Pessoa, Isabel Correia, and Pedro Ad ao</p>
<p>18 Microwave–assisted Catalytic Oxidation of Alcohols to Carbonyl Compounds 233<br /> Yauhen Yu. Karabach, Maximilian N. Kopylovich, Kamran T. Mahmudov, and Armando J. L. Pombeiro</p>
<p>19 Oxidation of Glycerol with Hydrogen Peroxide Catalyzed by Metal Complexes 247<br /> Dalmo Mandelli, Wagner A. Carvalho, Lidia S. Shul pina, Alexander M. Kirillov, Marina V. Kirillova,<br /> Armando J. L. Pombeiro, and Georgiy B. Shul pin</p>
<p>20 Involvement of an Acetato Ligand in the Reductive Elimination Step of the Rhodium–catalyzed Methanol Carbonylation 259<br /> Duc Hanh Nguyen, Nicolas Lassauque, Thomas Davin, Laurent Maron, Carole Le Berre, Philippe Serp, and Philippe Kalck</p>
<p>21 Half–sandwich Rhodium(III), Iridium(III), and Ruthenium(II) Complexes with Ancillary Pyrazole–based Ligands 269<br /> Claudio Pettinari, Riccardo Pettinari, Corrado Di Nicola, and Fabio Marchetti</p>
<p>22 Carbon–scorpionate Complexes in Oxidation Catalysis 285<br /> Lu´©¥sa M. D. R. S. Martins and Armando J. L. Pombeiro</p>
<p>23 Toward Chemoselective Bioconjugative Desulfitative Catalysis 295<br /> Lanny S. Liebeskind and Ethel C. Garnier–Amblard</p>
<p>24 Sulfoxide Redox Chemistry with Molybdenum Catalysts 305<br /> Maria Jos´e Calhorda and Luis F. Veiros</p>
<p>25 A New Family of Zirconium Complexes Anchored by Dianionic Cyclam–based Ligands: Syntheses,<br /> Structures, and Catalytic Applications 315<br /> Ana M. Martins, Rui F. Munh´a, Luis G. Alves, and Shanmuga Bharathi</p>
<p>26 Metal–organo Multicatalysis: An Emerging Concept 325<br /> Alexandre F. Trindade, Jo ao N. Rosa, F´abio M. F. Santos, and Pedro M. P. Gois</p>
<p>PART III ORGANOMETALLIC POLYMERIZATION CATALYSIS 343</p>
<p>27 Coordinative Chain Transfer Polymerisations and Copolymerisations by Means of Rare Earths<br /> Organometallic Catalysts for the Synthesis of Tailor–made Polymers 345<br /> Marc Visseaux, Thomas Chenal, and Philippe Zinck</p>
<p>28 Charge–neutral and Cationic Complexes of Large Alkaline Earths for Ring–opening Polymerization<br /> and Fine Chemicals Catalysis 359<br /> Jean–Fran¸cois Carpentier, Bo Liu, and Yann Sarazin</p>
<p>PART IV ORGANOMETALLIC POLYMERS AND MATERIALS 379</p>
<p>29 Organometallic Polymers 381<br /> Manuel Serrano–Ruiz, Franco Scalambra, and Antonio Romerosa</p>
<p>30 From Serendipity to Porosity: Synthesis and Reactivity of Coordination Polymers Based on Copper Trinuclear Triangular Motifs 407<br /> Luciano Pandolfo</p>
<p>31 Organometallic Nanoparticles 421<br /> Patricia Lara, Karine Philippot, Lise–Marie Lacroix, S´ebastien Lachaize, Nikos Liakakos, Katerina Soulantica, and Bruno Chaudret</p>
<p>32 Organometallic Compounds in the Synthesis of New Materials: Old Ligands, New Tricks 437<br /> Piotr Sobota and ¨©ukasz John</p>
<p>33 The Role of Organometallic Complexes in the Synthesis of Shaped Carbon Materials 445<br /> Neil J. Coville and Edward N. Nxumalo</p>
<p>34 Metal Catalysis in Fullerene Chemistry 459<br /> Salvatore Filippone, Enrique E. Maroto, A´ngel Mart´©¥n–Domenech, and Nazario Mart´©¥n</p>
<p>35 Organometallic Complexes of Sumanene 473<br /> Toru Amaya and Toshikazu Hirao</p>
<p>36 Advances in Luminescent Tetracoordinate Organoboron Compounds 485<br /> D. Suresh and Pedro T. Gomes</p>
<p>37 Mechanochemistry: A Tool in the Synthesis of Catalysts, Metallodrugs, and Metallopharmaceuticals 493<br /> V ania Andr´e, Clara S. B. Gomes, and M. Teresa Duarte</p>
<p>PART V ORGANOMETALLIC CHEMISTRY AND SUSTAINABLE ENERGY 501</p>
<p>38 Organometallic Complexes for Dye–sensitized Solar Cells (DSSC) 503<br /> Delele W. Ayele, Wei–Nein Su, John Rick, Hung–Ming Chen, Chun–Jern Pan, Nibret G. Akalework, and Bing–Joe Hwang</p>
<p>39 Synthetic Photosynthesis for the Conversion of Large Volumes of Carbon Dioxide into Energy–Rich Molecules: Saving Fossil Fuels by Recycling Carbon 513<br /> Michele Aresta and Angela Dibenedetto</p>
<p>40 Ionic Liquids for Hydrogen Storage: Opportunities for Organometallic Chemistry 529<br /> Martin H. G. Prechtl and Sebastian Sahler</p>
<p>PART VI BIOORGANOMETALLIC CHEMISTRY 543</p>
<p>41 Metal Carbonyls for CO–based Therapies: Challenges and Successes 545<br /> Carlos C. Rom ao and Helena L. A. Vieira</p>
<p>42 The Ferrocifen Family as Potent and Selective Antitumor Compounds: Mechanisms of Action 563<br /> G´erard Jaouen and Siden Top</p>
<p>43 On the Track to Cancer Therapy: Paving New Ways With Ruthenium Organometallics 581<br /> T ania S. Morais and M. Helena Garcia</p>
<p>44 Organometallic Chemistry of Rhenium and Technetium Fueled by Biomedical Applications 589<br /> Ant´onio Paulo, Goreti Ribeiro Morais, and Isabel Santos</p>
<p>45 Metal–based Indolobenzazepines and Indoloquinolines: From Moderate cdk Inhibitors to Potential Antitumor Drugs 605<br /> Michael F. Primik, Lukas K. Filak, and Vladimir B. Arion</p>
<p>46 Metal–based Chelates and Nanosystems as MRI Contrast Agents 619<br /> Sara Figueiredo and Carlos F. G. C. Geraldes</p>
<p>PART VII ORGANOMETALLIC ELECTROCHEMISTRY 631</p>
<p>47 Electrochemistry and Supramolecular Interactions of Ferrocifen Anticancer Drugs with Cyclodextrins and Lipid Bilayers: An Electrochemical Overview 633<br /> Olivier Buriez, Eric Labb´e, and Christian Amatore</p>
<p>48 Electrochemistry of Fischer Aminocarbene Complexes: Effects of Structure on Redox Properties, Electron Distribution, and Reaction Mechanisms 653<br /> Ji¢§r´©¥ Ludv´©¥k and Irena Hoskovcov´a</p>
<p>49 Electron Transfer–induced Coordination Changes in Organometallic Complexes with Non–innocent Hemilabile Ligands 667<br /> Wolfgang Kaim, Martina Bubrin, and Ralph H¨ubner</p>
<p>50 Redox Potential Structure Relationships and Parameterization in Characterization and Identification of Organometallic Compounds 677<br /> M. F´atima C. Guedes da Silva and Armando J. L. Pombeiro</p>
<p>51 Endohedral Metallofullerenes Today: More and More Versatile Ships in Multiform Bottles Electrochemistry of X–Ray Characterized Monometallofullerenes 691<br /> Fabrizia Fabrizi de Biani and Piero Zanello</p>
<p>POSTSCRIPT: A SHORT HISTORY OF THE ICOMC CONFERENCES 703<br /> Ekkehardt Hahn</p>
<p>INDEX 707</p>
<p>CONTRIBUTORS xv</p>
<p>PART I ACTIVATION AND FUNCTIONALIZATION OF CARBON SINGLE BONDS AND OF SMALL<br /> MOLECULES 1</p>
<p>1 Organometallic Complexes as Catalysts in Oxidation of C H Compounds 3<br /> Georgiy B. Shul pin</p>
<p>2 Toward Functionalization of Alkanes Under Environmentally Benign Conditions 15<br /> Armando J. L. Pombeiro</p>
<p>3 Self–assembled Multicopper Complexes and Coordination Polymers for Oxidation and Hydrocarboxylation of Alkanes 27<br /> Alexander M. Kirillov, Marina V. Kirillova, and Armando J. L. Pombeiro</p>
<p>4 Activation of C O and C F Bonds by Pincer–iridium Complexes 39<br /> Jason Hackenberg, Karsten Krogh–Jespersen, and Alan S. Goldman</p>
<p>5 Functionalization of sp2 and sp3 Carbon Centers Catalysed by Polyoxometalates and Metalloporphyrins 59<br /> M´ario M. Q. Sim oes, Isabel C. M. S. Santos, Maria Gra¸ca P. M. S. Neves, Ana M. V. Cavaleiro, and Jos´e A. S. Cavaleiro</p>
<p>6 Quasi–borinium Cation Based on Cobalt Bis(dicarbollide): Its Lewis Acidity and C H and C X Bond Activation 73<br /> V. I. Bregadze, I. B. Sivaev, I. D. Kosenko, I. A. Lobanova, Z. A. Starikova, and I. A. Godovikov</p>
<p>7 Transition–metal–promoted Functionalization of Carboranes 81<br /> Zaozao Qiu and Zuowei Xie</p>
<p>8 Weak Interactions and M H Bond Activation 97<br /> Elena Shubina, Natalia Belkova, Oleg Filippov, and Lina Epstein</p>
<p>PART II ORGANOMETALLIC SYNTHESIS AND CATALYSIS 111</p>
<p>9 Complexes with Protic N–Heterocyclic Carbene (NR,NH–NHC) Ligands 113<br /> F. Ekkehardt Hahn</p>
<p>10 Cyclopentadienyl–functionalized N–Heterocyclic Carbene Complexes of Iron and Nickel: Catalysts for Reductions 133<br /> Beatriz Royo</p>
<p>11 Palladium–(acyclic diaminocarbene) Species as Alternative to Palladium–(nitrogen heterocyclic carbenes) in Cross–coupling Catalysis 145<br /> Vadim P. Boyarskiy, Konstantin V. Luzyanin, and Vadim Yu. Kukushkin</p>
<p>12 Synthesis of Metallocenes Via Metathesis in Metal Coordination Spheres 157<br /> Antoni Pietrzykowski and W©©odzimierz Buchowicz</p>
<p>13 Metal–mediated [2 + 3] Dipolar Cycloaddition to Substrates with CN Triple Bond: Recent Advances 171<br /> Konstantin V. Luzyanin and Maxim L. Kznetsov</p>
<p>14 Coordination Chemistry of Oxazoline/Thiazoline–based P,N Ligands 185<br /> Shuanming Zhang, Roberto Pattacini, and Pierre Braunstein</p>
<p>15 Click Copper Catalyzed Azide–alkyne Cycloaddition (CuAAC) in Aqueous Medium 199<br /> Joaqu´©¥n Garc´©¥a–A´lvarez and Jose´ Gimeno</p>
<p>16 Organogold Catalysis: Homogeneous Gold–catalyzed Transformations for a Golden Jubilee 207<br /> Fabien Gagosz</p>
<p>17 Vanadium(IV) Complexes Derived from Aromatic o–Hydroxyaldehydes and Tyrosine Derivatives: Catalytic Evaluation in Sulfoxidations 227<br /> Jo ao Costa Pessoa, Isabel Correia, and Pedro Ad ao</p>
<p>18 Microwave–assisted Catalytic Oxidation of Alcohols to Carbonyl Compounds 233<br /> Yauhen Yu. Karabach, Maximilian N. Kopylovich, Kamran T. Mahmudov, and Armando J. L. Pombeiro</p>
<p>19 Oxidation of Glycerol with Hydrogen Peroxide Catalyzed by Metal Complexes 247<br /> Dalmo Mandelli, Wagner A. Carvalho, Lidia S. Shul pina, Alexander M. Kirillov, Marina V. Kirillova,<br /> Armando J. L. Pombeiro, and Georgiy B. Shul pin</p>
<p>20 Involvement of an Acetato Ligand in the Reductive Elimination Step of the Rhodium–catalyzed Methanol Carbonylation 259<br /> Duc Hanh Nguyen, Nicolas Lassauque, Thomas Davin, Laurent Maron, Carole Le Berre, Philippe Serp, and Philippe Kalck</p>
<p>21 Half–sandwich Rhodium(III), Iridium(III), and Ruthenium(II) Complexes with Ancillary Pyrazole–based Ligands 269<br /> Claudio Pettinari, Riccardo Pettinari, Corrado Di Nicola, and Fabio Marchetti</p>
<p>22 Carbon–scorpionate Complexes in Oxidation Catalysis 285<br /> Lu´©¥sa M. D. R. S. Martins and Armando J. L. Pombeiro</p>
<p>23 Toward Chemoselective Bioconjugative Desulfitative Catalysis 295<br /> Lanny S. Liebeskind and Ethel C. Garnier–Amblard</p>
<p>24 Sulfoxide Redox Chemistry with Molybdenum Catalysts 305<br /> Maria Jos´e Calhorda and Luis F. Veiros</p>
<p>25 A New Family of Zirconium Complexes Anchored by Dianionic Cyclam–based Ligands: Syntheses,<br /> Structures, and Catalytic Applications 315<br /> Ana M. Martins, Rui F. Munh´a, Luis G. Alves, and Shanmuga Bharathi</p>
<p>26 Metal–organo Multicatalysis: An Emerging Concept 325<br /> Alexandre F. Trindade, Jo ao N. Rosa, F´abio M. F. Santos, and Pedro M. P. Gois</p>
<p>PART III ORGANOMETALLIC POLYMERIZATION CATALYSIS 343</p>
<p>27 Coordinative Chain Transfer Polymerisations and Copolymerisations by Means of Rare Earths<br /> Organometallic Catalysts for the Synthesis of Tailor–made Polymers 345<br /> Marc Visseaux, Thomas Chenal, and Philippe Zinck</p>
<p>28 Charge–neutral and Cationic Complexes of Large Alkaline Earths for Ring–opening Polymerization<br /> and Fine Chemicals Catalysis 359<br /> Jean–Fran¸cois Carpentier, Bo Liu, and Yann Sarazin</p>
<p>PART IV ORGANOMETALLIC POLYMERS AND MATERIALS 379</p>
<p>29 Organometallic Polymers 381<br /> Manuel Serrano–Ruiz, Franco Scalambra, and Antonio Romerosa</p>
<p>30 From Serendipity to Porosity: Synthesis and Reactivity of Coordination Polymers Based on Copper Trinuclear Triangular Motifs 407<br /> Luciano Pandolfo</p>
<p>31 Organometallic Nanoparticles 421<br /> Patricia Lara, Karine Philippot, Lise–Marie Lacroix, S´ebastien Lachaize, Nikos Liakakos, Katerina Soulantica, and Bruno Chaudret</p>
<p>32 Organometallic Compounds in the Synthesis of New Materials: Old Ligands, New Tricks 437<br /> Piotr Sobota and ¨©ukasz John</p>
<p>33 The Role of Organometallic Complexes in the Synthesis of Shaped Carbon Materials 445<br /> Neil J. Coville and Edward N. Nxumalo</p>
<p>34 Metal Catalysis in Fullerene Chemistry 459<br /> Salvatore Filippone, Enrique E. Maroto, A´ngel Mart´©¥n–Domenech, and Nazario Mart´©¥n</p>
<p>35 Organometallic Complexes of Sumanene 473<br /> Toru Amaya and Toshikazu Hirao</p>
<p>36 Advances in Luminescent Tetracoordinate Organoboron Compounds 485<br /> D. Suresh and Pedro T. Gomes</p>
<p>37 Mechanochemistry: A Tool in the Synthesis of Catalysts, Metallodrugs, and Metallopharmaceuticals 493<br /> V ania Andr´e, Clara S. B. Gomes, and M. Teresa Duarte</p>
<p>PART V ORGANOMETALLIC CHEMISTRY AND SUSTAINABLE ENERGY 501</p>
<p>38 Organometallic Complexes for Dye–sensitized Solar Cells (DSSC) 503<br /> Delele W. Ayele, Wei–Nein Su, John Rick, Hung–Ming Chen, Chun–Jern Pan, Nibret G. Akalework, and Bing–Joe Hwang</p>
<p>39 Synthetic Photosynthesis for the Conversion of Large Volumes of Carbon Dioxide into Energy–Rich Molecules: Saving Fossil Fuels by Recycling Carbon 513<br /> Michele Aresta and Angela Dibenedetto</p>
<p>40 Ionic Liquids for Hydrogen Storage: Opportunities for Organometallic Chemistry 529<br /> Martin H. G. Prechtl and Sebastian Sahler</p>
<p>PART VI BIOORGANOMETALLIC CHEMISTRY 543</p>
<p>41 Metal Carbonyls for CO–based Therapies: Challenges and Successes 545<br /> Carlos C. Rom ao and Helena L. A. Vieira</p>
<p>42 The Ferrocifen Family as Potent and Selective Antitumor Compounds: Mechanisms of Action 563<br /> G´erard Jaouen and Siden Top</p>
<p>43 On the Track to Cancer Therapy: Paving New Ways With Ruthenium Organometallics 581<br /> T ania S. Morais and M. Helena Garcia</p>
<p>44 Organometallic Chemistry of Rhenium and Technetium Fueled by Biomedical Applications 589<br /> Ant´onio Paulo, Goreti Ribeiro Morais, and Isabel Santos</p>
<p>45 Metal–based Indolobenzazepines and Indoloquinolines: From Moderate cdk Inhibitors to Potential Antitumor Drugs 605<br /> Michael F. Primik, Lukas K. Filak, and Vladimir B. Arion</p>
<p>46 Metal–based Chelates and Nanosystems as MRI Contrast Agents 619<br /> Sara Figueiredo and Carlos F. G. C. Geraldes</p>
<p>PART VII ORGANOMETALLIC ELECTROCHEMISTRY 631</p>
<p>47 Electrochemistry and Supramolecular Interactions of Ferrocifen Anticancer Drugs with Cyclodextrins and Lipid Bilayers: An Electrochemical Overview 633<br /> Olivier Buriez, Eric Labb´e, and Christian Amatore</p>
<p>48 Electrochemistry of Fischer Aminocarbene Complexes: Effects of Structure on Redox Properties, Electron Distribution, and Reaction Mechanisms 653<br /> Ji¢§r´©¥ Ludv´©¥k and Irena Hoskovcov´a</p>
<p>49 Electron Transfer–induced Coordination Changes in Organometallic Complexes with Non–innocent Hemilabile Ligands 667<br /> Wolfgang Kaim, Martina Bubrin, and Ralph H¨ubner</p>
<p>50 Redox Potential Structure Relationships and Parameterization in Characterization and Identification of Organometallic Compounds 677<br /> M. F´atima C. Guedes da Silva and Armando J. L. Pombeiro</p>
<p>51 Endohedral Metallofullerenes Today: More and More Versatile Ships in Multiform Bottles Electrochemistry of X–Ray Characterized Monometallofullerenes 691<br /> Fabrizia Fabrizi de Biani and Piero Zanello</p>
<p>POSTSCRIPT: A SHORT HISTORY OF THE ICOMC CONFERENCES 703<br /> Ekkehardt Hahn</p>
<p>INDEX 707</p>