R Rios Torres
John Wiley & Sons
e druk, 2013
9781118203538
Stereoselective Organocatalysis – Bond Formation Methodologies and Activation Modes
Bond Formation Methodologies and Activation Modes
Specificaties
Gebonden, 674 blz.
|
Engels
John Wiley & Sons |
e druk, 2013
ISBN13: 9781118203538
Rubricering
Verwachte levertijd ongeveer 16 werkdagen
Samenvatting
This book covers the most important methodologies reported for stereoselective organocatalysis, based not only on the activation mode but also the type of bond formed. Starting with an introduction laying out the different activation modes, the chapters move on to describe the most important methodologies for the formation of key chemical bonds, including carbon–carbon (C–C), carbon–nitrogen (C–N), and carbon–halogen (C–X) bonds. It features an organization and approach useful for both students and practicing chemists in industry.
Specificaties
Inhoudsopgave
<p>PREFACE vii</p>
<p>CONTRIBUTORS ix</p>
<p>1. INTRODUCTION: A HISTORICAL POINT OF VIEW 1<br /> Ramon Rios and Xavier Companyó</p>
<p>2. ACTIVATION MODES IN ASYMMETRIC ORGANOCATALYSIS 11<br /> Albert Moyano</p>
<p>3. C C BOND FORMATION BY ALDOL REACTION 81<br /> Dorota Gryko and Dominika Walaszek</p>
<p>4. EXAMPLES OF METAL–FREE DIRECT CATALYTIC ASYMMETRIC MANNICH–TYPE REACTIONS USING AMINOCATALYSIS 129<br /> Armando Córdova</p>
<p>5. C C BOND FORMATION BY MICHAEL REACTION 147<br /> Yong Zhang and Wei Wang</p>
<p>6. C C BOND FORMATION BY DIELS ALDER AND OTHER PERICYCLIC REACTIONS 205<br /> Johan Franzén</p>
<p>7. N–HETEROCYCLIC CARBENE–CATALYZED C C BOND FORMATION 231<br /> Xiang–Yu Chen and Song Ye</p>
<p>8. a–ALKYLATION OF CARBONYL COMPOUNDS 267<br /> Marek Reme and Jan Veselý</p>
<p>9. OTHER REACTIONS FOR C C BOND FORMATION 313<br /> Yi–Xia Jia and Tiexin Zhang</p>
<p>10. CASCADE REACTIONS FORMING C C BONDS 351<br /> Ramon Rios, Jorge Esteban, and Xavier Companyó</p>
<p>11. ORGANOCATALYTIC C N BOND FORMATION 381<br /> Aitor Landa, Rosa López, Antonia Mielgo, Mikel Oiarbide, and Claudio Palomo</p>
<p>12. C O BOND FORMATION 433<br /> José Alemán and Mariola Tortosa</p>
<p>13. CARBON HALOGEN BOND FORMATION 465<br /> Stacey E. Brenner–Moyer</p>
<p>14. C OTHER ATOM BOND FORMATION (S, SE, B) 493<br /> Giorgio Della Sala and Alessandra Lattanzi</p>
<p>15. ENANTIOSELECTIVE ORGANOCATALYTIC REDUCTIONS 529<br /> Maurizio Benaglia, Martina Bonsignore, and Andrea Genoni</p>
<p>16. CASCADE REACTIONS FORMING BOTH C C BOND AND C HETEROATOM BOND 559<br /> Damien Bonne, Thierry Constantieux, Yoann Coquerel, and Jean Rodriguez</p>
<p>17. ORGANOCATALYSIS IN THE SYNTHESIS OF NATURAL PRODUCTS 587<br /> Yongcheng Ying and Xuefeng Jiang</p>
<p>INDEX 629</p>
<p>CONTRIBUTORS ix</p>
<p>1. INTRODUCTION: A HISTORICAL POINT OF VIEW 1<br /> Ramon Rios and Xavier Companyó</p>
<p>2. ACTIVATION MODES IN ASYMMETRIC ORGANOCATALYSIS 11<br /> Albert Moyano</p>
<p>3. C C BOND FORMATION BY ALDOL REACTION 81<br /> Dorota Gryko and Dominika Walaszek</p>
<p>4. EXAMPLES OF METAL–FREE DIRECT CATALYTIC ASYMMETRIC MANNICH–TYPE REACTIONS USING AMINOCATALYSIS 129<br /> Armando Córdova</p>
<p>5. C C BOND FORMATION BY MICHAEL REACTION 147<br /> Yong Zhang and Wei Wang</p>
<p>6. C C BOND FORMATION BY DIELS ALDER AND OTHER PERICYCLIC REACTIONS 205<br /> Johan Franzén</p>
<p>7. N–HETEROCYCLIC CARBENE–CATALYZED C C BOND FORMATION 231<br /> Xiang–Yu Chen and Song Ye</p>
<p>8. a–ALKYLATION OF CARBONYL COMPOUNDS 267<br /> Marek Reme and Jan Veselý</p>
<p>9. OTHER REACTIONS FOR C C BOND FORMATION 313<br /> Yi–Xia Jia and Tiexin Zhang</p>
<p>10. CASCADE REACTIONS FORMING C C BONDS 351<br /> Ramon Rios, Jorge Esteban, and Xavier Companyó</p>
<p>11. ORGANOCATALYTIC C N BOND FORMATION 381<br /> Aitor Landa, Rosa López, Antonia Mielgo, Mikel Oiarbide, and Claudio Palomo</p>
<p>12. C O BOND FORMATION 433<br /> José Alemán and Mariola Tortosa</p>
<p>13. CARBON HALOGEN BOND FORMATION 465<br /> Stacey E. Brenner–Moyer</p>
<p>14. C OTHER ATOM BOND FORMATION (S, SE, B) 493<br /> Giorgio Della Sala and Alessandra Lattanzi</p>
<p>15. ENANTIOSELECTIVE ORGANOCATALYTIC REDUCTIONS 529<br /> Maurizio Benaglia, Martina Bonsignore, and Andrea Genoni</p>
<p>16. CASCADE REACTIONS FORMING BOTH C C BOND AND C HETEROATOM BOND 559<br /> Damien Bonne, Thierry Constantieux, Yoann Coquerel, and Jean Rodriguez</p>
<p>17. ORGANOCATALYSIS IN THE SYNTHESIS OF NATURAL PRODUCTS 587<br /> Yongcheng Ying and Xuefeng Jiang</p>
<p>INDEX 629</p>