Structural and Electronic Paradigms in Cluster Chemistry

Specificaties
Paperback, 211 blz. | Engels
Springer Berlin Heidelberg | 0e druk, 2013
ISBN13: 9783662148167
Rubricering
Springer Berlin Heidelberg 0e druk, 2013 9783662148167
Onderdeel van serie Structure and Bonding
Verwachte levertijd ongeveer 9 werkdagen

Samenvatting

It is 25 years since the seminal papers describing the relationships between the skeletal geometrics and closed shell electronic requirements of metal clusters were originally published. The electron counting rules which developed from these papers, are now to be found in all undergraduate inorganic textbooks. This volume provides a contemporary account of recent applications of the methodology and the mathematical foundations of the rules. In addition it describes how it is possible to accomondate acception to the rules within a wider framework. The authors are the foremost authorities in the field and give a broad introduction to the area.

Specificaties

ISBN13:9783662148167
Taal:Engels
Bindwijze:paperback
Aantal pagina's:211
Uitgever:Springer Berlin Heidelberg
Druk:0

Inhoudsopgave

Mathematical cluster chemistry.- Metal-metal interactions in transition metal clusters with ?-donor ligands.- Electron count versus structural arrangement in clusters based on a cubic transition metal core with bridging main group elements.- Metallaboranes.- Clusters with interstitial atoms from the p-block: How do Wade's rules handle them?.- Diverse naked clusters of the heavy main-group elements. Electronic regularities and analogies.

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        Structural and Electronic Paradigms in Cluster Chemistry